# Ultraviolet catastrophe

The ultraviolet catastrophe is the error at short wavelengths in the Rayleigh–Jeans law (depicted as "classical theory" in the graph) for the energy emitted by an ideal black-body. The error, much more pronounced for short wavelengths, is the difference between the black curve (as classically predicted by the Rayleigh–Jeans law) and the blue curve (the measured curve as predicted by Planck's law).

The ultraviolet catastrophe, also called the Rayleigh–Jeans catastrophe, was the prediction of late 19th century/early 20th century classical physics that an ideal black body (also blackbody) at thermal equilibrium will emit radiation in all frequency ranges, emitting more energy as the frequency increases. By calculating the total amount of radiated energy (i.e., the sum of emissions in all frequency ranges), it can be shown that a blackbody is likely to release an arbitrarily high amount of energy. This would cause all matter to instantaneously radiate all of its energy until it is near absolute zero - indicating that a new model for the behaviour of blackbodies was needed.

The term "ultraviolet catastrophe" was first used in 1911 by Paul Ehrenfest, but the concept originated with the 1900 statistical derivation of the Rayleigh–Jeans law. The phrase refers to the fact that the Rayleigh–Jeans law accurately predicts experimental results at radiative frequencies below 105 GHz, but begins to diverge with empirical observations as these frequencies reach the ultraviolet region of the electromagnetic spectrum.[1] Since the first appearance of the term, it has also been used for other predictions of a similar nature, as in quantum electrodynamics and such cases as ultraviolet divergence.

## Problem

The ultraviolet catastrophe results from the equipartition theorem of classical statistical mechanics which states that all harmonic oscillator modes (degrees of freedom) of a system at equilibrium have an average energy of ${\displaystyle kT}$.

An example, from Mason's A History of the Sciences,[2] illustrates multi-mode vibration via a piece of string. As a natural vibrator, the string will oscillate with specific modes (the standing waves of a string in harmonic resonance), dependent on the length of the string. In classical physics, a radiator of energy will act as a natural vibrator. And, since each mode will have the same energy, most of the energy in a natural vibrator will be in the smaller wavelengths and higher frequencies, where most of the modes are.

According to classical electromagnetism, the number of electromagnetic modes in a 3-dimensional cavity, per unit frequency, is proportional to the square of the frequency. This therefore implies that the radiated power per unit frequency should follow the Rayleigh–Jeans law, and be proportional to frequency squared. Thus, both the power at a given frequency and the total radiated power is unlimited as higher and higher frequencies are considered: this is clearly unphysical as the total radiated power of a cavity is not observed to be infinite, a point that was made independently by Einstein and by Lord Rayleigh and Sir James Jeans in 1905.

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