Metallic hydrogen

A diagram showing the inside of Jupiter
Gas giants such as Jupiter (pictured above) and Saturn might contain large amounts of metallic hydrogen (depicted in grey) and metallic helium. [1]

Metallic hydrogen is a kind of degenerate matter, a phase of hydrogen in which it behaves like an electrical conductor. This phase was predicted in 1935 on theoretical grounds by Eugene Wigner and Hillard Bell Huntington. [2]

At high pressure and temperatures, metallic hydrogen might exist as a liquid rather than a solid, and researchers think it is present in large quantities in the hot and gravitationally compressed interiors of Jupiter, Saturn, and in some extrasolar planets. [3]

In October 2016, there were claims that metallic hydrogen had been observed in the laboratory at a pressure of around 495 gigapascals (4,950,000  bar; 4,890,000  atm; 71,800,000  psi). [4] In January 2017, scientists at Harvard University reported the first creation of metallic hydrogen in a laboratory, using a diamond anvil cell. [5] Several researchers in the field doubt this claim. [6] Some observations consistent with metallic behavior had been reported earlier, such as the observation of new phases of solid hydrogen under static conditions [7] [8] and, in dense liquid deuterium, electrical insulator-to-conductor transitions associated with an increase in optical reflectivity. [9]

Theoretical predictions

Metallization of hydrogen under pressure

Though often placed at the top of the alkali metal column in the periodic table, hydrogen does not, under ordinary conditions, exhibit the properties of an alkali metal. Instead, it forms diatomic H2 molecules, analogous to halogens and non-metals in the second row of the periodic table, such as nitrogen and oxygen. Diatomic hydrogen is a gas that, at atmospheric pressure, liquefies and solidifies only at very low temperature (20 degrees and 14 degrees above absolute zero, respectively). Eugene Wigner and Hillard Bell Huntington predicted that under an immense pressure of around 25 GPa (250000 atm; 3600000 psi) hydrogen would display metallic properties: instead of discrete H2 molecules (which consist of two electrons bound between two protons), a bulk phase would form with a solid lattice of protons and the electrons delocalized throughout. [2] Since then, producing metallic hydrogen in the laboratory has been described as "...the holy grail of high-pressure physics." [10]

The initial prediction about the amount of pressure needed was eventually shown to be too low. [11] Since the first work by Wigner and Huntington, the more modern theoretical calculations were pointing toward higher but nonetheless potentially accessible metallization pressures of 100 GPa and higher.

Liquid metallic hydrogen

Helium-4 is a liquid at normal pressure near absolute zero, a consequence of its high zero-point energy (ZPE). The ZPE of protons in a dense state is also high, and a decline in the ordering energy (relative to the ZPE) is expected at high pressures. Arguments have been advanced by Neil Ashcroft and others that there is a melting point maximum in compressed hydrogen, but also that there might be a range of densities, at pressures around 400 GPa (3,900,000 atm), where hydrogen would be a liquid metal, even at low temperatures. [12] [13]

Superconductivity

In 1968, Neil Ashcroft suggested that metallic hydrogen might be a superconductor, up to room temperature (290 K or 17 °C), far higher than any other known candidate material. This hypothesis is based on an expected strong coupling between conduction electrons and lattice vibrations. [14]

Possibility of novel types of quantum fluid

Presently known "super" states of matter are superconductors, superfluid liquids and gases, and supersolids. Egor Babaev predicted that if hydrogen and deuterium have liquid metallic states, they might have quantum ordered states that cannot be classified as superconducting or superfluid in the usual sense. Instead, they might represent two possible novel types of quantum fluids: superconducting superfluids and metallic superfluids. Such fluids were predicted to have highly unusual reactions to external magnetic fields and rotations, which might provide a means for experimental verification of Babaev's predictions. It has also been suggested that, under the influence of magnetic field, hydrogen might exhibit phase transitions from superconductivity to superfluidity and vice versa. [15] [16] [17]

Lithium alloying reduces requisite pressure

In 2009, Zurek et al. predicted that the alloy LiH6 would be a stable metal at only one quarter of the pressure required to metallize hydrogen, and that similar effects should hold for alloys of type LiHn and possibly other related alloys of type Lin. [18]

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